Bibliothèque de L'IMIST/CNRST

This volume includes papers presented at the second International Workshop on <IT>Oxide-based Systems at the Crossroads of Chemistry</IT>, held at Villa Olmo in Como, Italy, 8-11 October. The selected papers present the highlights of recent research in the field of oxide structure. A wide range of oxidic materials, including real oxides, zeolites and layer-structured systems, is considered and described in terms of preparation methods, structural characterization and the relation between active sites, structure and catalytic properties. The application of the most powerful simulation and physical-chemical techniques show their usefulness in discovering and explaining structural and dynamic properties of complex materials. Moreover the development of sophisticated spectroscopical and analytical techniques are shown to significantly improve the growth of surface oxide science, generating new tools for the knowledge of catalyst structure and reaction mechanisms. An interesting feature is the inclusion of papers which show the mutual roles of experiment and theoretical models.

Selected papers. High-resolution electron microscopy, neutron diffraction with isotopic substitution and x-ray absorption fine structure for the characterisation of active sites in oxide catalysts (John Meurig Thomas). Location of Bronsted and cation sites in dehydrated zeolites: a comparison (A. Alberti <IT>et al</IT>.). Characteristics in the photocatalytic reactivity of the tetrahedrally coordinated ti-oxide species designed within various types of zeolites and on support surfaces (M. Anpo <IT>et al</IT>.). Chemisorption and catalytic properties of gold nanoparticles on different oxides: electronic or structural effects? (F. Boccuzzi, A. Chiorino). The vibrational spectra of phosphorous oxynitride at high pressures (M. Capecchi <IT>et al</IT>.). Dissociative adsorption of H<INF>2</INF> on defect sites of MgO: A combined IR spectroscopic and quantum chemical study (M. Cavalleri<IT> et al</IT>.). Modification of redox and catalytic properties of Kegging-type, Sb-doped P/Mo polyoxometalates in the selective oxidation of isobutane to methacrylic acid: control of preparation conditions (F. Cavani <IT>et al</IT>.). Surface properties of mesoporous Ti-MCM-48 and their modifications produced by silylation (V. Dellarocca <IT>et al</IT>.). Computer simulations of ethane sorbed in an aluminophosphate molecular sieve (P. Demontis <IT>et al</IT>.). Intracage chemistry: nitrite to nitrate oxidation via molecular oxygen. A car parrinello study. (E. Fois <IT>et al</IT>.). Synthesis, spectroscopic and catalytic properties of cobalt and copper ions in aluminophosphates with chabasite-like structure. Studies of the NO reactivity (A. Frache <IT>et al</IT>.). Local structures of active sites on Mo-MCM-41 mesoporous molecular sieves and their photocatalytic reactivity for the decomposition of NOx (I. Higashimoto<IT> et al</IT>.). The factorial experimental design applied to the zeolite synthesis (A. Katovic <IT>et al</IT>.). Synthesis and characterization of dye-containing MCM.

Includes bibliographical references and index.

Description based on print version record.