TY  - BOOK
AU  - Centi,,Gabriele
AU  - Wichterlova,,Blanka
AU  - Bell,,Alexis T.
TI  - Catalysis by unique metal ion structures in solid matrices: from science to application
T2  - Nato science series ii: mathematics, physics and chemistry
SN  - 0792368754
U1  - 541 
PY  - 2001///
CY  - [S.l.]
PB  - Springer
KW  - Catalysis
KW  - Mathematics & science
KW  - Physical chemistry
KW  - Science
KW  - Science/Mathematics
KW  - Chemistry - Physical & Theoretical
KW  - Science / Chemistry / Industrial & Technical
KW  - Science / Chemistry / Inorganic
KW  - Science / Chemistry / Physical & Theoretical
KW  - Chemistry
N1  - Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing how an understanding of it is essential to the development of a new generation of solid catalysts. There are also exciting opportunities to shape the catalytic properties of the transition metal cations in microporous and mesoporous matrices. The book covers both theoretical and experimental aspects, including the distribution of framework Al atoms in Si-rich zeolites, distribution and siting of charge-exchanged metal cations, electronic, adsorptive and catalytic properties of metal cations, and correlation of metal cation structure and siting with catalytic activity
ER  -